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Molecules

Title:		Synthesis of the Sex Pheromone of the Tea Tussock Moth Based on a Resource Chemistry Strategy
Author(s):		Zhang HL; Sun ZF; Zhou LN; Liu L; Zhang T; Du ZT;
Address:		"State Key Laboratory of Crop Stress Biology in Arid Areas, Northwest A&F University, Yangling 712100, China. honglizhang@126.com. Shaanxi Key Laboratory for Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, China. sunzhifeng2018@163.com. College of Chemistry and Pharmacy, Northwest A&F University, Yangling 712100, China. sunzhifeng2018@163.com. College of Chemistry and Pharmacy, Northwest A&F University, Yangling 712100, China. Zhou18792419302@163.com. College of Chemistry and Pharmacy, Northwest A&F University, Yangling 712100, China. m18706733265@163.com. College of Chemistry and Pharmacy, Northwest A&F University, Yangling 712100, China. fuzitong@163.com. College of Chemistry and Pharmacy, Northwest A&F University, Yangling 712100, China. duzt@nwsuaf.edu.cn. Key Laboratory of Botanical Pesticide R&D in Shaanxi Province, Yangling 712100, China. duzt@nwsuaf.edu.cn"
Journal Title:		Molecules
Year:		2018
Volume:		20180604
Issue:		6
Page Number:		-
DOI:		10.3390/molecules23061347
ISSN/ISBN:		1420-3049 (Electronic) 1420-3049 (Linking)
Abstract:		"Synthesis of the sex pheromone of the tea tussock moth in 33% overall yield over 10 steps was achieved. Moreover, the chiral pool concept was applied in the asymmetric synthesis. The synthesis used a chemical available on a large-scale from recycling of wastewater from the steroid industry. The carbon skeleton was constructed using the C4+C5+C8 strategy. Based on this strategy, the original chiral center was totally retained"
Keywords:		Animals Carbon-13 Magnetic Resonance Spectroscopy Drug Industry Moths/*chemistry Oxidation-Reduction Proton Magnetic Resonance Spectroscopy Recycling Sex Attractants/*chemical synthesis Wastewater insect sex pheromone resource chemistry tea tussock moth t;
Notes:		"MedlineZhang, Hong-Li Sun, Zhi-Feng Zhou, Lu-Nan Liu, Lu Zhang, Tao Du, Zhen-Ting eng Switzerland 2018/06/06 Molecules. 2018 Jun 4; 23(6):1347. doi: 10.3390/molecules23061347"