| Title: | Volatile organic compounds emitted by conventional and 'green' cleaning products in the U.S. market |
| Author(s): | Temkin AM; Geller SL; Swanson SA; Leiba NS; Naidenko OV; Andrews DQ; |
| Address: | "Environmental Working Group, 1250 I St NW Suite 1000, Washington DC, 20005, USA. Electronic address: alexis@ewg.org. Environmental Working Group, 1250 I St NW Suite 1000, Washington DC, 20005, USA. Amazon.com, Inc., Seattle, WA, 98109, USA" |
| DOI: | 10.1016/j.chemosphere.2023.139570 |
| ISSN/ISBN: | 1879-1298 (Electronic) 0045-6535 (Linking) |
| Abstract: | "Exposure to cleaning products has been associated with harm to the respiratory system, neurotoxicity, harm to the reproductive system, and elevated risk of cancer, with greatest adverse impacts for workers exposed in an occupational setting. Social and consumer interest in cleaning products that are safer for health created a market category of 'green' products defined here as products advertised as healthier, non-toxic, or free from harmful chemicals as well as products with a third-party certification for safety or environmental features. In the present study we examined the air quality impacts of cleaning products and air fresheners, measuring the number, concentrations, and emission factors of volatile organic compounds (VOCs) in an air chamber following product application. Across seven common product categories, 30 products were tested overall including 14 conventional, 9 identified as 'green' with fragrance, and 7 identified as 'green' and fragrance-free. A total of 530 unique VOCs were quantified with 205 additional VOCs detected below the limits of quantification. Of the quantifiable VOCs, 193 were considered hazardous according to either the California's Department of Toxic Substances Control Candidate Chemicals List or the European Chemical Agency's Classification and Labeling Inventory. The total concentration of VOCs and total emission factors across all products with detections ranged from below limits of detection to 18,708 mug/m(3), 38,035 mug/g product and 3803 mug/application. Greater total concentration, total emission factors, and numbers of VOCs were generally observed in conventional cleaning products compared to products identified as 'green', particularly compared to fragrance-free products. A hazard index approach was utilized to assess relative risk from measured VOC emissions. The five products with the highest hazard indices were conventional products with emissions of 2-butoxyethanol, isopropanol, toluene and chloroform. Overall, this analysis suggests that the use of 'green' cleaning products, especially fragrance-free products, may reduce exposure to VOC emissions" |
| Keywords: | Humans *Volatile Organic Compounds 2-Propanol Certification Chloroform Genitalia *Perfume Air chamber testing Cleaning product Indoor air quality VOCs Volatile organic compounds; |
| Notes: | "MedlineTemkin, Alexis M Geller, Samara L Swanson, Sydney A Leiba, Nneka S Naidenko, Olga V Andrews, David Q eng England 2023/09/15 Chemosphere. 2023 Nov; 341:139570. doi: 10.1016/j.chemosphere.2023.139570. Epub 2023 Sep 12" |
