Title: | "Thermal conversion of elephant grass (Pennisetum purpureum Schum) to bio-gas, bio-oil and charcoal" |
Author(s): | Strezov V; Evans TJ; Hayman C; |
Address: | "Graduate School of the Environment, Macquarie University, Sydney, NSW 2109, Australia. vstrezov@gse.mq.edu.au" |
DOI: | 10.1016/j.biortech.2008.02.039 |
ISSN/ISBN: | 0960-8524 (Print) 0960-8524 (Linking) |
Abstract: | "Elephant grass is an abundant, fast growing plant with significant potential as a renewable energy source and for conversion to higher calorific value fuels. This work investigates thermal conversion of elephant grass to bio-gas, bio-oil and charcoal under two heating rates of 10 and 50 degrees C/min. The energy required to pyrolyse elephant grass was evaluated using computer aided thermal analysis technique, while composition of the resultant bio-gas and bio-oil products were monitored with gas chromatographic and mass spectroscopic techniques. At 500 degrees C, the bio-gas compounds consisted primarily of CO2 and CO with small amounts of methane and higher hydrocarbon compounds. The heat of combustion of the bio-gas compounds was estimated to be 3.7-7.4 times higher than the heat required to pyrolyse elephant grass under both heating rates, which confirms that the pyrolysis process can be self-maintained. Faster heating rate was found to increase the amount of liquid products by 10%, while charcoal yields remained almost the same at 30%. The bio-oil mainly consisted of organic acids, phthalate esters, benzene compounds and amides. The amount of organic acids and benzene compounds were significantly reduced at 50 degrees C/min, while the yields of phthalate esters and naphthalene compounds increased. The difference in bio-oil composition with increased heating rate is believed to be associated with the reduction of the secondary reactions of pyrolysis, which are more pronounced under lower heating rate" |
Keywords: | *Bioelectric Energy Sources Charcoal/*chemical synthesis Minerals/analysis Molecular Weight Pennisetum/*metabolism Plant Oils/*chemical synthesis/chemistry *Temperature Volatilization; |
Notes: | "MedlineStrezov, Vladimir Evans, Tim J Hayman, Chris eng England 2008/04/15 Bioresour Technol. 2008 Nov; 99(17):8394-9. doi: 10.1016/j.biortech.2008.02.039. Epub 2008 Apr 11" |