Title: | Utilization of activated carbon as an effective replacement for a commercialized three-bed sorbent (Carbopack) to quantitate aromatic hydrocarbons in ambient air |
Author(s): | Lee YS; Maitlo HA; Kim KH; Kwon EE; Lee MH; Kim JC; Song HN; Szulejko JE; |
Address: | "Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul, 04763, Republic of Korea. Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul, 04763, Republic of Korea. Electronic address: kkim61@hanyang.ac.kr. Department of Environment and Energy, Sejong University, Seoul, 05005, Republic of Korea. Electronic address: ekwon74@sejong.ac.kr. Department of Civil and Environmental Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-Gu, Seoul, 05029, South Korea. Electronic address: jckim@konkuk.ac.kr. ACEN Co., Ltd, Yeongtong-Gu Dukyong Dearo 1556-16, Suwon-Si, Gyeonggi-Do, 16670, Republic of Korea" |
DOI: | 10.1016/j.envres.2019.108802 |
ISSN/ISBN: | 1096-0953 (Electronic) 0013-9351 (Linking) |
Abstract: | "The potential use of activated carbon (AC) as an inexpensive and effective alternative sorbent material in thermal desorption is presented and validated for the analysis of aromatic volatile organic compounds (VOCs) such as benzene, toluene, m-xylene, and styrene (BTXS) in air. The optimum desorption conditions of an AC sampling tube (2 mg AC bed) were determined and compared with a commercial three-bed (Carbopack; C + B + X) tube sampler as a reference. The AC sampler exhibited good linearity (R(2)?ª+>?ª+0.99) and reproducibility (RSE of 2.38?ª++/-?ª+0.21%) for BTXS analysis. The AC tube sampler showed good storability (up to 3?ª+d) and excellent recyclability (up to 50 cycles). An analysis of BTXS in ambient air showed excellent agreement between AC and CBX (bias?ª+ª+5%). The 1% breakthrough volume values for 2?ª+mg AC, when tested at 100?ª+ppb of benzene as a sole component or in a BTXS mixture, were 10,000 or 5000?ª+L?ª+g(-1), respectively. The results of this study support the performance of AC as a suitable medium for sampling VOCs as reliable as high-cost commercial sorbent products" |
Keywords: | *Air Pollutants Benzene *Charcoal Reproducibility of Results *Volatile Organic Compounds Activated carbon Carbopack Desorption Thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS) Volatile organic compounds; |
Notes: | "MedlineLee, Yoon-Seo Maitlo, Hubdar Ali Kim, Ki-Hyun Kwon, Eilhann E Lee, Min-Hee Kim, Jo-Chun Song, Hee-Nam Szulejko, Jan E eng Research Support, Non-U.S. Gov't Netherlands 2019/10/20 Environ Res. 2019 Dec; 179(Pt A):108802. doi: 10.1016/j.envres.2019.108802. Epub 2019 Oct 10" |