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Nanomaterials (Basel)

Title:		Synergy Effect of Au and SiO(2) Modification on SnO(2) Sensor Properties in VOCs Detection in Humid Air
Author(s):		Gulevich D; Rumyantseva M; Gerasimov E; Khmelevsky N; Tsvetkova E; Gaskov A;
Address:		"Chemistry Department, Moscow State University, 119991 Moscow, Russia. Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia. LISM, Moscow State Technological University Stankin, 127055 Moscow, Russia. Bauman Moscow State Technical University, 105005 Moscow, Russia"
Journal Title:		Nanomaterials (Basel)
Year:		2020
Volume:		20200423
Issue:		4
Page Number:		-
DOI:		10.3390/nano10040813
ISSN/ISBN:		2079-4991 (Print) 2079-4991 (Electronic) 2079-4991 (Linking)
Abstract:		"Nanocomposites based on Au- and SiO(2)-modified SnO(2) were studied as sensitive materials for ethanol and benzene detection in dry (RH = 1%) and humid (RH = 20%) air. Modification of SnO(2) by amorphous SiO(2) (13 mol.%) was effectuated by hydrothermal synthesis; modification by Au nanoparticles (1 wt.%) was carried out via impregnation by citrate-stabilized Au sol. The composition of the samples was determined by X-ray fluorescent spectroscopy and energy-dispersive X-ray spectroscopy. The microstructure was characterized by XRD, HRTEM, and low-temperature nitrogen adsorption. The surface groups were investigated by XPS, TPR-H(2), and FTIR spectroscopy. DRIFT spectroscopy was performed to investigate the interaction between ethanol and the surface of the synthesized materials. Studies of the sensor properties have shown that in all cases the most sensitive is the SnO(2)/SiO(2)-Au nanocomposite. This material retains high sensitivity even in a humid atmosphere. The obtained results are discussed in terms of the synergistic effect of two modifiers (Au and SiO(2)) in the formation of sensor properties of SnO(2)/SiO(2)-Au nanocomposites"
Keywords:		Au clusters gas sensor humid air hydrothermal synthesis silicon dioxide thermal stability tin dioxide volatile organic compounds;
Notes:		"PubMed-not-MEDLINEGulevich, Dayana Rumyantseva, Marina Gerasimov, Evgeny Khmelevsky, Nikolay Tsvetkova, Elena Gaskov, Alexander eng 19-13-00245/Russian Science Foundation/ Switzerland 2020/04/29 Nanomaterials (Basel). 2020 Apr 23; 10(4):813. doi: 10.3390/nano10040813"