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J Org Chem


Title:Enantiodivergent synthesis of both enantiomers of gypsy moth pheromone disparlure
Author(s):Prasad KR; Anbarasan P;
Address:"Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India. prasad@orgchem.iisc.ernet.in"
Journal Title:J Org Chem
Year:2007
Volume:20070317
Issue:8
Page Number:3155 - 3157
DOI: 10.1021/jo070060o
ISSN/ISBN:0022-3263 (Print) 0022-3263 (Linking)
Abstract:"Enantiodivergent synthesis of both (-)- and (+)-disparlure, a bioactive pheromone, possessing a cis-epoxide has been accomplished. The key step involves the cross metathesis of a chiral homoallylic alcohol derived from l-(+)-tartaric acid"
Keywords:Alkanes/*metabolism Animals Moths/*metabolism Pheromones/*metabolism Stereoisomerism;
Notes:"MedlinePrasad, Kavirayani R Anbarasan, Pazhamalai eng Research Support, Non-U.S. Gov't 2007/03/21 J Org Chem. 2007 Apr 13; 72(8):3155-7. doi: 10.1021/jo070060o. Epub 2007 Mar 17"

 
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