| Title: | Characterizing the emission behaviors of cumulative VOCs from automotive solvent-based paint sludge |
| Author(s): | Liu Z; Huang Z; Yan Y; Liu T; Lv T; Chen Y; Yang J; Die Q; Zhao Y; Huang Q; |
| Address: | "State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China; The State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092, China. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. Electronic address: huangzc@craes.org.cn. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. China National Environmental Monitoring Centre, Beijing, 100012, China. The State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. The State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai, 200092, China. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China. Electronic address: huangqf@craes.org.cn" |
| DOI: | 10.1016/j.jenvman.2022.115369 |
| ISSN/ISBN: | 1095-8630 (Electronic) 0301-4797 (Linking) |
| Abstract: | "Volatile organic compounds (VOCs) diffused from paint sludge are potential hazard contributing significantly to environmental pollution and exposure to them can cause severe health issues. In this paper, a diffusion-controlled model was firstly developed for characterizing the emission behaviors of cumulative VOCs from automotive solvent-based paint sludge based on the worst field management scenario. The presented model is characterized by two key parameters: the diffusion coefficient (D(m)) and the initial emittable concentration (C(m,0)), which can be simultaneously obtained by our proposed ER-history method. Four major components were detected including 1-butanol, butyl acetate and 1,2,4-trimethylbenzene and 1-ethyl-4-methylbenzene. In addition, the model was validated by using environmental data in a ventilated test chamber, proving that the model is reliable and convincing. However, relative deviations of 1-butanol and butyl acetate are larger than those of 1,2,4-trimethylbenzene and 1-ethyl-4-methylbenzene, indicating that the model is more accurate for predicting hydrophobic VOCs release than those of hydrophilic VOCs. Besides, an increase in C(m,0) and D(m) tends to enhance VOCs cumulation release. Our studies provide new insight into experimental designs for rapid model parameters measurement and a sound basis for estimating VOCs cumulative release from paint sludge as well as for hazardous waste" |
| Keywords: | 1-Butanol *Air Pollutants/analysis Environmental Monitoring/methods Paint Sewage Solvents *Volatile Organic Compounds/analysis Diffusing behavior Model Paint sludge Parameters VOCs; |
| Notes: | "MedlineLiu, Zewei Huang, Zechun Yan, Yusen Liu, Tingting Lv, Tianfeng Chen, Yu Yang, Jinzhong Die, Qingqi Zhao, Youcai Huang, Qifei eng England 2022/05/28 J Environ Manage. 2022 Sep 1; 317:115369. doi: 10.1016/j.jenvman.2022.115369. Epub 2022 May 24" |
