| Title: | High Efficiency Membranes Based on PTMSP and Hyper-Crosslinked Polystyrene for Toxic Volatile Compounds Removal from Wastewater |
| Author(s): | Golubev G; Sokolov S; Rokhmanka T; Makaev S; Borisov I; Khashirova S; Volkov A; |
| Address: | "A.V. Topchiev Institute of Petrochemical Synthesis RAS, 29 Leninsky prospekt, 119991 Moscow, Russia. Department of Organic Chemistry and Macromolecular Compounds, Kabardino-Balkar State University named after H.M. Berbekov, 173 Chernyshevsky St., 360004 Nalchik, Kabardino-Balkarian Republic, Russia" |
| ISSN/ISBN: | 2073-4360 (Electronic) 2073-4360 (Linking) |
| Abstract: | "For the first time, membranes based on poly(1-trimethylsilyl-1-propyne) (PTMSP) with 5-50 wt% loading of hyper-crosslinked polystyrene sorbent particles (HCPS) were obtained; the membranes were investigated for the problem of effective removal of volatile organic compounds from aqueous solutions using vacuum pervaporation. The industrial HCPS sorbent Purolite Macronet MN200 was chosen due to its high sorption capacity for organic solvents. It has been found that the membranes are asymmetric when HCPS content is higher than 30 wt%; scanning electron microscopy of the cross-sections the membranes demonstrate that they have a clearly defined thin layer, consisting mainly of PTMSP, and a thick porous layer, consisting mainly of HCPS. The transport and separation characteristics of PTMSP membranes with different HCPS loading were studied during the pervaporation separation of binary and multicomponent mixtures of water with benzene, toluene and xylene. It was shown that the addition of HCPS up to 30 wt% not only increases the permeate fluxes by 4-7 times, but at the same time leads to 1.5-2 fold increase in the separation factor. It was possible to obtain separation factors exceeding 1000 for all studied mixtures at high permeate fluxes (0.5-1 kg/m(2)?O+h) in pervaporation separation of binary solutions" |
| Keywords: | Btx Ptmsp aromatic hydrocarbons benzene mixed matrix membranes o-xylene pervaporation polystyrene removal toluene; |
| Notes: | "PubMed-not-MEDLINEGolubev, Georgy Sokolov, Stepan Rokhmanka, Tatyana Makaev, Sergey Borisov, Ilya Khashirova, Svetlana Volkov, Alexey eng 20- 79-00363/Russian Science Foundation/ Switzerland 2022/07/28 Polymers (Basel). 2022 Jul 20; 14(14):2944. doi: 10.3390/polym14142944" |
