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Talanta


Title:"HPLC Coupled with in-line photolysis, hydride generation and flame atomic-absorption spectrometry for the speciation of tin in natural waters"
Author(s):Ebdon L; Hill SJ; Jones P;
Address:"Plymouth Analytical Chemistry Research Unit, Department of Environmental Sciences, Polytechnic South West, Drake Circus, Plymouth, Devon PL4 8AA, England"
Journal Title:Talanta
Year:1991
Volume:38
Issue:6
Page Number:607 - 611
DOI: 10.1016/0039-9140(91)80143-n
ISSN/ISBN:0039-9140 (Print) 0039-9140 (Linking)
Abstract:"The use of an in-line photolysis coil in a continuous-flow system of high-performance liquid chromatography coupled with hydride generation and flame atomic-absorption spectrometry for the speciation of tin in natural waters is described. Irradiation with ultraviolet light is shown to convert tributyltin into organic tin(IV), from which a volatile hydride can be produced in the conventional way. The effect of various conditions on the analytical performance is discussed. A detection limit of 2 ng for tin was obtained, and the tin species could be completely separated within 6 min. Use of the technique for quantification of tributyltin compounds in local coastal waters is described"
Keywords:
Notes:"PubMed-not-MEDLINEEbdon, L Hill, S J Jones, P eng Netherlands 1991/06/01 Talanta. 1991 Jun; 38(6):607-11. doi: 10.1016/0039-9140(91)80143-n"

 
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