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J Nanosci Nanotechnol


Title:"Heterogeneous Decomposition of Volatile Organic Compounds by Visible-Light Activated N, C, S-Embedded Titania"
Author(s):Chun HH; Jo WK;
Address:
Journal Title:J Nanosci Nanotechnol
Year:2016
Volume:16
Issue:5
Page Number:4544 - 4553
DOI: 10.1166/jnn.2016.10976
ISSN/ISBN:1533-4899 (Electronic) 1533-4880 (Linking)
Abstract:"In this study, a N-, C-, and S-doped titania (NCS-TiO2) composite was prepared by combining the titanium precursor with a single dopant source, and the photocatalytic activity of this system for the decomposition of volatile organic compounds (VOCs) at indoor-concentration levels, under exposure to visible light, was examined. The NCS-TiO2 composite and the pure TiO2 photocatalyst, used as a reference, were characterized via X-ray diffraction, scanning electron microscopy, ultraviolet-visible diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. The average efficiencies of benzene, toluene, ethyl benzene, and o-xylene decomposition using NCS-TiO2 for were 70, 87, -100, and -100%, respectively, whereas the values obtained using the pure TiO2 powder were -0, 18, 49, and 51%, respectively. These results suggested that, for the photocatalytic decomposition of toxic VOCs under visible-light exposure conditions, NCS-TiO2 was superior to the reference photocatalyst. The decomposition efficiencies of the target VOCs were inversely related to the initial concentration and relative humidity as well as to the air-flow rate. The decomposition efficiencies of the target chemicals achieved with a conventional lamp/NCS-TiO2 system were higher than those achieved with a light emitting diode/NCS-TiO2 system. Overall, NCS-TiO2 can be used for the efficient decomposition of VOCs under visible-light exposure, if the operational conditions are optimized"
Keywords:
Notes:"PubMed-not-MEDLINEChun, Ho-Hwan Jo, Wan-Kuen eng Research Support, Non-U.S. Gov't 2016/08/03 J Nanosci Nanotechnol. 2016 May; 16(5):4544-53. doi: 10.1166/jnn.2016.10976"

 
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