Title: | "Synthesis of (1R,7Z)-1-methyl-7-hexadecenyl acetate, the female sex pheromone of the honey locust gall midge" |
Address: | "Photosensitive Materials Research Center, Toyo Gosei Co, Ltd, Inzai, Chiba, Japan" |
Journal Title: | Biosci Biotechnol Biochem |
ISSN/ISBN: | 1347-6947 (Electronic) 0916-8451 (Linking) |
Abstract: | "(1R,7Z)-1-Methyl-7-hexadecenyl acetate (1), the female sex pheromone of the honey locust gall midge (Dasineura gleditchiae), was synthesized from 6-hepten-1-ol in an 8.9% overall yield (eight steps). Hydrolytic kinetic resolution of (+/-)-1,2-epoxy-8-heptadecyne was the key step in the synthesis" |
Keywords: | Acetates/*chemical synthesis Animals Chironomidae/*chemistry/physiology Fatty Alcohols/*chemistry Female Gas Chromatography-Mass Spectrometry Magnetic Resonance Spectroscopy Sex Attractants/*chemical synthesis Stereoisomerism; |
Notes: | "MedlineShikichi, Yasumasa Mori, Kenji eng England 2012/07/13 Biosci Biotechnol Biochem. 2012; 76(7):1419-21. doi: 10.1271/bbb.120265. Epub 2012 Jul 7" |