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Materials (Basel)

Title:		Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion
Author(s):		Li J; Zuo S; Yang P; Qi C;
Address:		"Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, China. sfzuo@126.com. Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, China. sfzuo@usx.edu.cn. Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, China. yangpeng1898@163.com. Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, China. qichenze@usx.edu.cn"
Journal Title:		Materials (Basel)
Year:		2017
Volume:		20170815
Issue:		8
Page Number:		-
DOI:		10.3390/ma10080949
ISSN/ISBN:		1996-1944 (Print) 1996-1944 (Electronic) 1996-1944 (Linking)
Abstract:		"A new functional AlNi-pillared clays (AlNi-PILC) with a large surface area and pore volume was synthesized. The performance of adsorption/desorption-catalytic combustion over CeO(2-)modified Pd/AlNi-PILC catalysts was also studied. The results showed that the d(001)-value and specific surface area (S(BET)) of AlNi-PILC reached 2.11 nm and 374.8 m(2)/g, respectively. The large S(BET) and the d(001)-value improved the high capacity for benzene adsorption. Also, the strong interaction between PdCe mixed oxides and AlNi-PILC led to the high dispersion of PdO and CeO(2) on the support, which was responsible for the high catalytic performance. Especially, 0.2% Pd/12.5% Ce/AlNi-PILC presented high performance for benzene combustion at 240 degrees C and high CO(2) selectivity. Also, the combustion temperatures were lower compared to the desorption temperatures, which demonstrated that it could accomplish benzene combustion during the desorption process. Furthermore, its activity did not decrease after continuous reaction for 1000 h in dry air, and it also displayed good resistance to water and the chlorinated compound, making it a promising catalytic material for the elimination of volatile organic compounds"
Keywords:		AlNi-PILC Pd-Ce Tpd/tpsr benzene catalytic combustion;
Notes:		"PubMed-not-MEDLINELi, Jingrong Zuo, Shufeng Yang, Peng Qi, Chenze eng Switzerland 2017/08/16 Materials (Basel). 2017 Aug 15; 10(8):949. doi: 10.3390/ma10080949"