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Proc Natl Acad Sci U S A


Title:Self-assembling amphiphilic molecules: Synthesis in simulated interstellar/precometary ices
Author(s):Dworkin J; Deamer D; Sandford S; Allamandola L;
Address:"Astrochemistry Laboratory, National Aeronautics and Space Administration Ames Research Center, Moffett Field, CA 94035-1000, USA"
Journal Title:Proc Natl Acad Sci U S A
Year:2001
Volume:98
Issue:3
Page Number:815 - 819
DOI: 10.1073/pnas.98.3.815
ISSN/ISBN:0027-8424 (Print) 1091-6490 (Electronic) 0027-8424 (Linking)
Abstract:"Interstellar gas and dust constitute the primary material from which the solar system formed. Near the end of the hot early phase of star and planet formation, volatile, less refractory materials were transported into the inner solar system as comets and interplanetary dust particles. Once the inner planets had sufficiently cooled, late accretionary infall seeded them with complex organic compounds [Oro, J. (1961) Nature (London) 190, 389-390; Delsemme, A. H. (1984) Origins Life 14, 51-60; Anders, E. (1989) Nature (London) 342, 255-257; Chyba, C. F. & Sagan, C. (1992) Nature (London) 355, 125-131]. Delivery of such extraterrestrial compounds may have contributed to the organic inventory necessary for the origin of life. Interstellar ices, the building blocks of comets, tie up a large fraction of the biogenic elements available in molecular clouds. In our efforts to understand their synthesis, chemical composition, and physical properties, we report here that a complex mixture of molecules is produced by UV photolysis of realistic, interstellar ice analogs, and that some of the components have properties relevant to the origin of life, including the ability to self-assemble into vesicular structures"
Keywords:"*Astronomy/methods *Ice *Meteoroids Models, Chemical *Organic Chemicals;"
Notes:"MedlineDworkin, J Deamer, D Sandford, S Allamandola, L eng Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. 2001/02/07 Proc Natl Acad Sci U S A. 2001 Jan 30; 98(3):815-9. doi: 10.1073/pnas.98.3.815"

 
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