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Chemosphere


Title:Influence of indoor environmental factors on mass transfer parameters and concentrations of semi-volatile organic compounds
Author(s):Wei W; Mandin C; Ramalho O;
Address:"University of Paris-Est, Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), 84 Avenue Jean Jaures, Champs sur Marne, 77447 Marne la Vallee Cedex 2, France. Electronic address: Wenjuan.WEI@cstb.fr. University of Paris-Est, Scientific and Technical Center for Building (CSTB), Health and Comfort Department, French Indoor Air Quality Observatory (OQAI), 84 Avenue Jean Jaures, Champs sur Marne, 77447 Marne la Vallee Cedex 2, France"
Journal Title:Chemosphere
Year:2018
Volume:20171218
Issue:
Page Number:223 - 235
DOI: 10.1016/j.chemosphere.2017.12.072
ISSN/ISBN:1879-1298 (Electronic) 0045-6535 (Linking)
Abstract:"Semi-volatile organic compounds (SVOCs) in indoor environments can partition among the gas phase, airborne particles, settled dust, and available surfaces. The mass transfer parameters of SVOCs, such as the mass transfer coefficient and the partition coefficient, are influenced by indoor environmental factors. Subsequently, indoor SVOC concentrations and thus occupant exposure can vary depending on environmental factors. In this review, the influence of six environmental factors, i.e., indoor temperature, humidity, ventilation, airborne particle concentration, source loading factor, and reactive chemistry, on the mass transfer parameters and indoor concentrations of SVOCs was analyzed and tentatively quantified. The results show that all mass transfer parameters vary depending on environmental factors. These variations are mostly characterized by empirical equations, particularly for humidity. Theoretical calculations of these parameters based on mass transfer mechanisms are available only for the emission of SVOCs from source surfaces when airborne particles are not present. All mass transfer parameters depend on the temperature. Humidity influences the partition of SVOCs among different phases and is associated with phthalate hydrolysis. Ventilation has a combined effect with the airborne particle concentration on SVOC emission and their mass transfer among different phases. Indoor chemical reactions can produce or eliminate SVOCs slowly. To better model the dynamic SVOC concentration indoors, the present review suggests studying the combined effect of environmental factors in real indoor environments. Moreover, interactions between indoor environmental factors and human activities and their influence on SVOC mass transfer processes should be considered"
Keywords:"Air Pollutants/analysis/*pharmacology Air Pollution, Indoor/*analysis Dust/analysis Environment Human Activities Humans Humidity Models, Theoretical Phthalic Acids Volatile Organic Compounds/*analysis Emission Mass transfer Modeling Partition SVOCs;"
Notes:"MedlineWei, Wenjuan Mandin, Corinne Ramalho, Olivier eng Review England 2017/12/22 Chemosphere. 2018 Mar; 195:223-235. doi: 10.1016/j.chemosphere.2017.12.072. Epub 2017 Dec 18"

 
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