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Environ Sci Technol


Title:Intermediate-Volatility Organic Compound Emissions from Nonroad Construction Machinery under Different Operation Modes
Author(s):Qi L; Liu H; Shen X; Fu M; Huang F; Man H; Deng F; Shaikh AA; Wang X; Dong R; Song C; He K;
Address:"State Key Joint Laboratory of ESPC, School of Environment , Tsinghua University , Beijing 100084 , China. State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex , Beijing 100084 , China. Beijing Municipal Environmental Monitoring Center , Beijing 100048 , China. State Environment Protection Key Laboratory of Vehicle Emission Control and Simulation (VECS) , Beijing 100084 , China. Vehicle Emission Control Center (VECC) , Chinese Research Academy of Environmental Sciences , Beijing 100012 , China"
Journal Title:Environ Sci Technol
Year:2019
Volume:20191118
Issue:23
Page Number:13832 - 13840
DOI: 10.1021/acs.est.9b01316
ISSN/ISBN:1520-5851 (Electronic) 0013-936X (Linking)
Abstract:"Intermediate-volatility organic compounds (IVOCs) have been found as important sources for secondary organic aerosol (SOA) formation. IVOC emissions from nonroad construction machineries (NRCMs), including two road rollers and three motor graders, were characterized under three operation modes using an improved portable emission measurement system. The fuel-based IVOC emission factors (EFs) of NRCMs varied from 245.85 to 1802.19 mg/kg.fuel, which were comparable at magnitudes to the reported results of an ocean-going ship and on-road diesel vehicles without filters. The discrepancy of IVOC EFs is significant within different operation modes. IVOC EFs under the idling mode were 1.24-3.28 times higher than those under moving/working modes. Unspeciated b-alkanes and cyclic compounds, which were the unresolved components in IVOCs at the molecular level, accounted for approximately 91% of total IVOCs from NRCMs. The SOA production potential analysis shows that IVOCs dominated SOA formation of NRCMs. Our results demonstrate that IVOC emissions from NRCMs are non-negligible. Thus, an accurate estimation of their IVOC emissions would benefit the understanding of SOA formation in the urban atmosphere"
Keywords:Aerosols *Air Pollutants Atmosphere Vehicle Emissions *Volatile Organic Compounds Volatilization;
Notes:"MedlineQi, Lijuan Liu, Huan Shen, Xiu'e Fu, Mingliang Huang, Feifan Man, Hanyang Deng, Fanyuan Shaikh, Asad Ali Wang, Xiaotong Dong, Rui Song, Cheng He, Kebin eng 2019/11/07 Environ Sci Technol. 2019 Dec 3; 53(23):13832-13840. doi: 10.1021/acs.est.9b01316. Epub 2019 Nov 18"

 
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