Title: | A general method for the synthesis of nonracemic trans-epoxides: concise syntheses of trans-epoxide-containing insect sex pheromones |
Address: | "Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, V5A 1S6, Canada" |
ISSN/ISBN: | 1523-7060 (Print) 1523-7052 (Linking) |
Abstract: | "A general method for the synthesis of chiral nonracemic trans-epoxides has been developed that provides rapid access to alkyl-, alkenyl-, alkynyl-, and phenyl-substituted trans-epoxides from aldehydes. This methodology has also been applied in concise and high-yielding syntheses of both trans-epoxide containing insect sex pheromones" |
Keywords: | "Aldehydes/chemistry Epoxy Compounds/*chemical synthesis/chemistry Fatty Acids, Unsaturated/*chemical synthesis/chemistry Molecular Structure Sex Attractants/*chemical synthesis/chemistry Stereoisomerism;" |
Notes: | "MedlineKang, Baldip Britton, Robert eng Research Support, Non-U.S. Gov't 2007/11/03 Org Lett. 2007 Nov 22; 9(24):5083-6. doi: 10.1021/ol702273n. Epub 2007 Nov 2" |