« Previous AbstractProduction of volatile phenols by Pichia manshurica and Pichia membranifaciens isolated from spoiled wines and cellar environment in Patagonia    Next Abstract[Variation in sex pheromone composition in large fruit-tree tortrix Archips podana Scop. (Lepidoptera: Tortricidae)] »

Ind Eng Chem Res

Title:		Treatment of a Complex Emulsion of a Surfactant with Chlorinated Organic Compounds from Lindane Wastes under Alkaline Conditions by Air Stripping
Author(s):		Saez P; Garcia-Cervilla R; Santos A; Romero A; Lorenzo D;
Address:		"Chemical Engineering and Materials Department, Complutense University of Madrid, 28040 Madrid, Spain"
Journal Title:		Ind Eng Chem Res
Year:		2023
Volume:		20230207
Issue:		7
Page Number:		3282 - 3293
DOI:		10.1021/acs.iecr.2c03722
ISSN/ISBN:		0888-5885 (Print) 1520-5045 (Electronic) 0888-5885 (Linking)
Abstract:		"Surfactant-enhanced aquifer remediation is commonly applied in polluted sites with dense non-aqueous phase liquids (DNAPLs). This technique transfers the contamination from subsoil to an extracted emulsion, which requires further treatment. This work investigated the treatment of a complex emulsion composed of a nonionic surfactant and real DNAPL formed of chlorinated organic compounds (COCs) and generated as a lindane production waste by air stripping under alkaline conditions. The influence of the surfactant (1.5-15 g.L(-1)), COC concentrations (2.3-46.9 mmol.L(-1)), and temperature (30-60 degrees C) on the COC volatilization was studied and modeled in terms of an apparent constant of Henry at pH > 12. In addition, the surfactant stability was studied as a function of temperature (20-60 degrees C) and surfactant (2-10 g.L(-1)), COC (0-70.3 mmol.L(-1)), and NaOH (0-4 g.L(-1)) concentrations. A kinetic model was successfully proposed to explain the loss of surfactant capacity (SCL). The results showed that alkali and temperature caused the SCL by hydrolysis of the surfactant molecule. The increasing surfactant concentration decreased the COC volatility, whereas the temperature improved the COC volatilization. Finally, the volatilization of COCs in alkaline emulsions by air stripping (3 L.h(-1)) was performed to evaluate the treatment of an emulsion composed of the COCs (17.6 mmol.kg(-1)) and surfactant (3.5 and 7 g.L(-1)). The air stripping was successfully applied to remove COCs (>90%), reaching an SCL of 80% at 60 degrees C after 8 h. Volatilization can remove COCs from emulsions and break them, enhancing their further disposal"
Keywords:
Notes:		"PubMed-not-MEDLINESaez, Patricia Garcia-Cervilla, Raul Santos, Aurora Romero, Arturo Lorenzo, David eng 2023/03/01 Ind Eng Chem Res. 2023 Feb 7; 62(7):3282-3293. doi: 10.1021/acs.iecr.2c03722. eCollection 2023 Feb 22"