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Chemosphere

Title:		Oxidation of volatile organic compounds on SBA-15 mesoporous molecular sieves modified with manganese
Author(s):		Orlov A; Klinowski J;
Address:		"Department of Material Science and Engineering, State University of New York at Stony Brook, Stony Brook, NY 11794, USA"
Journal Title:		Chemosphere
Year:		2009
Volume:		20081031
Issue:		2
Page Number:		344 - 348
DOI:		10.1016/j.chemosphere.2008.08.049
ISSN/ISBN:		1879-1298 (Electronic) 0045-6535 (Linking)
Abstract:		"Catalytic combustion of volatile organic compounds, such as propene, has been studied on manganese modified mesoporous molecular sieves. Powder X-ray diffraction, (29)Si nuclear magnetic resonance, nitrogen sorption and transmission electron microscopy show that the SBA-15 mesoporous silica molecular sieve can be modified with manganese using Mn(2)(CO)(10) or Mn(O(2)CMe)(2) without significant distortion of the host structure. The two products were catalytically active in propene oxidation, with SBA-15 modified with Mn(2)(CO)(10) showing significantly higher activity, possibly due to higher Mn content, than SBA-15 modified with Mn(O(2)CMe)(2)"
Keywords:		"Adsorption Magnetic Resonance Spectroscopy Manganese/*chemistry Microscopy, Electron, Transmission Oxidation-Reduction Silicon Dioxide/*chemistry Volatile Organic Compounds/*chemistry X-Ray Diffraction;"
Notes:		"MedlineOrlov, Alexander Klinowski, Jacek eng England 2008/11/04 Chemosphere. 2009 Jan; 74(2):344-8. doi: 10.1016/j.chemosphere.2008.08.049. Epub 2008 Oct 31"