| Title: | "Reversible Absorption of Volatile Organic Compounds by Switchable-Hydrophilicity Solvents: A Case Study of Toluene with N,N-Dimethylcyclohexylamine" |
| Author(s): | Li Y; Chang H; Yan H; Tian S; Jessop PG; |
| Address: | "Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, Yunnan 650500, China. School of Pharmacy, Liaocheng University, Liaocheng 252059, China. Department of Chemistry, Queen's University, Kingston K7L 3N6, Canada" |
| ISSN/ISBN: | 2470-1343 (Electronic) 2470-1343 (Linking) |
| Abstract: | "Absorption is one of the most important treatment technologies for the removal of volatile organic compounds (VOCs) from tail gases, yet the separation of the absorbents and VOCs remains challenging because of concerns related to environmental impact and large energy requirements. Herein, we explored an absorption and desorption process using N,N-dimethylcyclohexylamine (CyNMe(2)) as a representative switchable-hydrophilicity solvent (SHS) and toluene as a representative VOC. The results showed that in comparison to common absorbents, CyNMe(2) exhibits excellent toluene absorption performance. Desorption efficiencies of toluene from CyNMe(2) of up to 94% were achieved by bubbling CO(2) at 25 degrees C, and separation efficiencies of CyNMe(2) from water up to 90% were achieved by bubbling N(2) at 60 degrees C. Even after five absorption-desorption cycles, the toluene absorption capacity of CyNMe(2) was comparable with that of the fresh absorbent, suggesting that CyNMe(2) retains its absorption capacity. We demonstrate an innovative and reversible remediation strategy of VOCs based on SHSs, and the results indicate that SHSs can be used as an alternative to common absorbents for the removal of VOCs to reduce environmental pollution and energy consumption" |
| Notes: | "PubMed-not-MEDLINELi, Yingjie Chang, Haiyu Yan, Hui Tian, Senlin Jessop, Philip G eng 2021/01/19 ACS Omega. 2020 Dec 30; 6(1):253-264. doi: 10.1021/acsomega.0c04443. eCollection 2021 Jan 12" |
