Title: | "Identification, syntheses, and characterization of the geometric isomers of 9,11-hexadecadienal from female pheromone glands of the sugar cane borer Diatraea saccharalis" |
Author(s): | Santangelo EM; Coracini M; Witzgall P; Correa AG; Unelius CR; |
Address: | "Department of Chemistry, Organic Chemistry, The Royal Institute of Technology, SE-10044 Stockholm, Sweden" |
ISSN/ISBN: | 0163-3864 (Print) 0163-3864 (Linking) |
Abstract: | "Chemical analysis of the pheromone glands of the sugar cane borer Diatraea saccharalis has shown the presence of the four geometric isomers of 9,11-hexadecadienal (1-4), in addition to hexadecanal and (Z)-hexadec-11-enal. We here report the syntheses and characterization of compounds 1-4. One starting material, 9-decen-1-ol, has been used to obtain all of them via divergent synthetic routes" |
Keywords: | "Aldehydes/*chemical synthesis/*chemistry Alkadienes/*chemical synthesis/*chemistry Animals Brazil Female Lepidoptera/*chemistry Mass Spectrometry Nuclear Magnetic Resonance, Biomolecular Pheromones/*chemical synthesis/*chemistry Stereoisomerism;" |
Notes: | "MedlineSantangelo, Ellen M Coracini, Myrian Witzgall, Peter Correa, Arlene G Unelius, C Rikard eng Research Support, Non-U.S. Gov't 2002/06/29 J Nat Prod. 2002 Jun; 65(6):909-15. doi: 10.1021/np010551i" |