Title: | "Enantiomeric synthesis of dominicalure, aggregation pheromone of lesser grain borer,Rhyzopertha dominica (F.)" |
Address: | "Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, People's Republic of China" |
ISSN/ISBN: | 0098-0331 (Print) 0098-0331 (Linking) |
Abstract: | "(S)-(+)-1-Methylbutyl (E)-2-methyl-2-pentenoate,1, and (S)-(+)-1-methylbutyl (E)-2,4-dimethyl-2-pentenoate2, the aggregation pheromone for lesser grain borerRhyzopertha dominica (F). were synthesized from crotylaldehyde in an overall yield of 30%. The chiral intermediate6 was prepared in 90% enantiomer excess, employing the Sharpless asymmetric epoxidation" |
Notes: | "PubMed-not-MEDLINELin-Yu, L Guo-Qiang, L eng 1990/06/01 J Chem Ecol. 1990 Jun; 16(6):1921-5. doi: 10.1007/BF01020505" |