| Title: | Development of a HS-SPME/GC-MS method for the analysis of volatile organic compounds from fabrics for forensic reconstruction applications |
| Author(s): | Gherghel S; Morgan RM; Arrebola-Liebanas J; Romero-Gonzalez R; Blackman CS; Garrido-Frenich A; Parkin IP; |
| Address: | "UCL Department of Security and Crime Science, 35 Tavistock Square, London WC1H 9EZ, United Kingdom; UCL Centre for the Forensic Sciences, 35 Tavistock Square, London WC1H 9EZ, United Kingdom; Research Group 'Analytical Chemistry of Contaminants', Department of Chemistry and Physics, Research Centre for Agricultural and Food Biotechnology (BITAL), University of Almeria, Agrifood Campus of International Excellence, ceiA3, E-04120 Almeria, Spain; UCL Department of Chemistry, 20 Gordon Street, London WC1H 0AJ, United Kingdom. Electronic address: simona.gherghel.14@ucl.ac.uk. UCL Department of Security and Crime Science, 35 Tavistock Square, London WC1H 9EZ, United Kingdom; UCL Centre for the Forensic Sciences, 35 Tavistock Square, London WC1H 9EZ, United Kingdom. Research Group 'Analytical Chemistry of Contaminants', Department of Chemistry and Physics, Research Centre for Agricultural and Food Biotechnology (BITAL), University of Almeria, Agrifood Campus of International Excellence, ceiA3, E-04120 Almeria, Spain. UCL Department of Chemistry, 20 Gordon Street, London WC1H 0AJ, United Kingdom" |
| DOI: | 10.1016/j.forsciint.2018.07.015 |
| ISSN/ISBN: | 1872-6283 (Electronic) 0379-0738 (Linking) |
| Abstract: | "An analytical method for the determination of trace amounts of volatile organic compounds (VOCs) relevant to the cosmetics industry was optimised, validated and employed for the analysis of commercial perfumes. The method used a combination of headspace solid phase microextraction (HS-SPME) and gas chromatography-mass spectrometry (GC-MS). In addition to fibre type, three different HS-SPME extraction conditions were investigated simultaneously, namely incubation time, extraction time and extraction temperature, using a central composite design in order to determine the optimal conditions for the extraction of VOCs of interest. The main figures of merit of the proposed method (calibration range, limits of detection and quantification, trueness and precision) were evaluated for six different VOCs in both natural and synthetic fibres in order to validate it and verify its capability for the proposed application. The validated method was applied for the analysis of traces of commercial perfumes from fabrics, and the VOCs of interest were successfully quantified. This simple, highly sensitive, and robust method has the potential to represent a powerful approach for forensic reconstructions where perfumes have transferred between individuals, such as during assaults and sexual assaults" |
| Keywords: | *Clothing Forensic Sciences/methods Gas Chromatography-Mass Spectrometry Humans Perfume/*chemistry Reproducibility of Results Solid Phase Microextraction Volatile Organic Compounds/*analysis Gc-ms Hs-spme Perfume analysis Trace evidence Validation Volatil; |
| Notes: | "MedlineGherghel, Simona Morgan, Ruth M Arrebola-Liebanas, Javier Romero-Gonzalez, Roberto Blackman, Chris S Garrido-Frenich, Antonia Parkin, Ivan P eng Ireland 2018/08/05 Forensic Sci Int. 2018 Sep; 290:207-218. doi: 10.1016/j.forsciint.2018.07.015. Epub 2018 Jul 25" |
