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Sci Rep

Title:		Highly efficient electronic sensitization of non-oxidized graphene flakes on controlled pore-loaded WO3 nanofibers for selective detection of H2S molecules
Author(s):		Choi SJ; Choi C; Kim SJ; Cho HJ; Hakim M; Jeon S; Kim ID;
Address:		"Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 291 Daehak-ro, Yuseong-gu, Daejeon 305-701, Republic of Korea. Department of Materials Science and Engineering and Graphene Research Center of KI for the NanoCentury, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea. Platforms Engineering Group, Intel Corporation, Haifa 31015, Israel"
Journal Title:		Sci Rep
Year:		2015
Volume:		20150128
Issue:
Page Number:		8067 -
DOI:		10.1038/srep08067
ISSN/ISBN:		2045-2322 (Electronic) 2045-2322 (Linking)
Abstract:		"Tailoring of semiconducting metal oxide nanostructures, which possess controlled pore size and concentration, is of great value to accurately detect various volatile organic compounds in exhaled breath, which act as potential biomarkers for many health conditions. In this work, we have developed a very simple and robust route for controlling both the size and distribution of spherical pores in electrospun WO3 nanofibers (NFs) via a sacrificial templating route using polystyrene colloids with different diameters (200 nm and 500 nm). A tentacle-like structure with randomly distributed pores on the surface of electrospun WO3 NFs were achieved, which exhibited improved surface area as well as porosity. Porous WO3 NFs with enhanced surface area exhibited high gas response (Rair/Rgas = 43.1 at 5 ppm) towards small and light H2S molecules. In contrast, porous WO3 NFs with maximized pore diameter showed a high response (Rair/Rgas = 2.8 at 5 ppm) towards large and heavy acetone molecules. Further enhanced sensing performance (Rair/Rgas = 65.6 at 5 ppm H2S) was achieved by functionalizing porous WO3 NFs with 0.1 wt% non-oxidized graphene (NOGR) flakes by forming a Schottky barrier (DeltaPhi = 0.11) at the junction between the WO3 NFs (Phi = 4.56 eV) and NOGR flakes (Phi = 4.67 eV), which showed high potential for the diagnosis of halitosis"
Keywords:
Notes:		"PubMed-not-MEDLINEChoi, Seon-Jin Choi, Chanyong Kim, Sang-Joon Cho, Hee-Jin Hakim, Meggie Jeon, Seokwoo Kim, Il-Doo eng Research Support, Non-U.S. Gov't England 2015/01/30 Sci Rep. 2015 Jan 28; 5:8067. doi: 10.1038/srep08067"