« Previous Abstract"Structural significance of the geminal-dimethyl group of (+)-trans-verbenyl acetate, sex pheromone mimic of the American cockroach"    Next AbstractSmall-molecule inhibitors of the Rce1p CaaX protease »

J Chem Ecol

Title:		"Studies on relationship between activity and electron density on carbonyl oxygen in sex pheromone mimics of the American cockroach, part XI"
Author(s):		Manabe S; Nishino C; Matsushita K;
Address:		"Mitsubishi-Kasei Institute of Life Sciences, 11 Minamiooya Machida-shi, 194, Tokyo, Japan"
Journal Title:		J Chem Ecol
Year:		1985
Volume:		11
Issue:		9
Page Number:		1275 - 1287
DOI:		10.1007/BF01024115
ISSN/ISBN:		0098-0331 (Print) 0098-0331 (Linking)
Abstract:		"From the relationship between structures of the 2alpha-substituents of verbanyl analogs and their sex pheromone activities to the American cockroach, electron density of the carbonyl oxygen atom in the substituent, as estimated by the [(17)O]NMR chemical shift, was estimated to be an important factor which influenced the activity, in addition to length of the substituent and the position of the carbonyl group. (+)-Verbanyl methylcarbonate (XX), possessing the highest electron density on the carbonyl oxygen atom, showed the strongest activity among the analogs"
Keywords:
Notes:		"PubMed-not-MEDLINEManabe, S Nishino, C Matsushita, K eng 1985/09/01 J Chem Ecol. 1985 Sep; 11(9):1275-87. doi: 10.1007/BF01024115"