| Title: | From metal-organic framework to morphology- and size-controlled 3D mesoporous Cr(2)O(3) toward a high surface area and enhanced volatile organic compound oxidation catalyst |
| Author(s): | Li X; Zhao Q; Qiao J; Zhang Q; Zhou X; |
| Address: | "Center for Aircraft Fire and Emergency, Civil Aviation University of China Tianjin 300300 China zhouxm@nankai.edu.cn" |
| ISSN/ISBN: | 2046-2069 (Electronic) 2046-2069 (Linking) |
| Abstract: | "Morphology- and size-controlled 3D mesoporous Cr(2)O(3) have always been a research hotspot due to their wide applications. Herein, we for the first time report that the carbonized Cr-MOFs can ignite spontaneously at room temperature and form the corresponding 3D mesoporous Cr(2)O(3) with high specific surface areas (219.25 to 303.44 cm(2) g(-1)). More importantly, the shape and size of 3D mesoporous Cr(2)O(3) can be well controlled by a facile adjustment of the Cr-MOF synthesis conditions. Furthermore, these materials showed an exceptionally high catalytic performance in formaldehyde oxidation. These results are predicted to offer a novel method in the design and synthesis of 3D porous Cr(2)O(3)" |
| Notes: | "PubMed-not-MEDLINELi, Xiutao Zhao, Qichen Qiao, Junyu Zhang, Qingsong Zhou, Xiaomeng eng England 2019/04/08 RSC Adv. 2019 Apr 8; 9(19):10865-10869. doi: 10.1039/c9ra00206e. eCollection 2019 Apr 3" |
