| Title: | Distinguishing between halogenated alkanes containing the same halogen based on the reaction kinetic parameter using negative ion mobility spectrometry at atmospheric pressure |
| Author(s): | Han H; Du S; Yan Y; Liu X; Zhu Q; Shi R; Xi S; Liu F; Zhao Z; Chu Y; |
| Address: | "Anhui Province Key Laboratory of Medical Physics and Technology, Institute of Health and Medical Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences Hefei 230031 P. R. China ychu@aiofm.ac.cn. School of Mathematics and Physics, Hebei University of Engineering Handan 056038 PR China hanhy0226@163.com hanwzl@163.com. School of Information and Electrical Engineering, Hebei University of Engineering Handan 056038 PR China yylhhy@163.com" |
| ISSN/ISBN: | 2046-2069 (Electronic) 2046-2069 (Linking) |
| Abstract: | "Electron adsorption ionization ion mobility spectrometry can be used to detect halogen-containing volatile organic compounds with high sensitivity. However, this traditional electron attachment detection method cannot distinguish between volatile organic compounds containing the same halogen. For different organic compounds containing the same halogen, the product ions formed by the dissociation electron attachment process are the same. In this article, we propose a novel negative corona discharge ion mobility spectrometry method to distinguish between and detect halogenated alkanes containing the same halogen according to the different electron attachment rates and reaction kinetic parameters of the different halogenated alkanes. Although these halogenated alkanes, which contain the same halogen, produce the same type of ions through the electron attachment process, their electron attachment rates are different from each other. In this work, the kinetic information is used as the fingerprint information for the tested samples to distinguish different halogenated alkanes. Five halogenated alkanes were successfully detected using this method. The results show that the method based on the electron attachment rate constant is feasible for the determination of halogenated alkanes containing the same halogen" |
| Notes: | "PubMed-not-MEDLINEHan, Haiyan Du, Shihu Yan, Yongliang Liu, Xiuhong Zhu, Qiaofen Shi, Ruili Xi, Sixing Liu, Feng Zhao, Zhi Chu, Yannan eng England 2020/08/10 RSC Adv. 2020 Aug 10; 10(49):29441-29449. doi: 10.1039/d0ra01284j. eCollection 2020 Aug 5" |
