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J Phys Chem A

Title:		OH-Radical Oxidation of Surface-Active cis-Pinonic Acid at the Air-Water Interface
Author(s):		Enami S; Sakamoto Y;
Address:		"The Hakubi Center for Advanced Research, Kyoto University , Kyoto 606-8302, Japan. Research Institute for Sustainable Humanosphere, Kyoto University , Uji 611-0011, Japan. PRESTO, Japan Science and Technology Agency , Kawaguchi 332-0012, Japan. Graduate School of Human and Environmental Studies, Kyoto University , Kyoto, 606-8316, Japan. Graduate School of Global Environmental Studies, Kyoto University , Kyoto, 606-8501, Japan"
Journal Title:		J Phys Chem A
Year:		2016
Volume:		20160509
Issue:		20
Page Number:		3578 - 3587
DOI:		10.1021/acs.jpca.6b01261
ISSN/ISBN:		1520-5215 (Electronic) 1089-5639 (Linking)
Abstract:		"Gaseous biogenic volatile organic compounds (BVOCs) are immediately oxidized by gaseous oxidants to form BVOC-acids that rapidly condense onto aqueous aerosol phase and thus contribute to the growth of atmospheric particles. Because BVOC-acids are highly hydrophobic and hence surface-active in nature, it seems critical to study the oxidation by gaseous hydroxyl radical (.OH(g)) at the air-water interface. Here we report on the fast (70%) of products would be emitted into the gas-phase during the heterogeneous .OH-oxidations. Our results suggest .OH-oxidations of amphiphilic BVOC-acids at the air-water interface may play a far more significant role in photochemical aging process of aqueous aerosols than previously assumed"
Keywords:
Notes:		"PubMed-not-MEDLINEEnami, Shinichi Sakamoto, Yosuke eng 2016/04/22 J Phys Chem A. 2016 May 26; 120(20):3578-87. doi: 10.1021/acs.jpca.6b01261. Epub 2016 May 9"