| Title: | Sonolytic reactions of phenanthrene in organic extraction solutions |
| Address: | "Department of Civil and Environmental Engineering and Geodetic Science, The Ohio State University, 470 Hitchcock Hall, 2070 Neil Ave., Columbus, OH 43210, USA" |
| DOI: | 10.1016/j.chemosphere.2006.05.029 |
| ISSN/ISBN: | 0045-6535 (Print) 0045-6535 (Linking) |
| Abstract: | "Ultrasonic extraction is a common method used to extract semi-volatile and nonvolatile organic compounds such as polycyclic aromatic hydrocarbons (PAHs) from solid matrices. However, ultrasonic energy has been suspected to lead to undesired reactions of the solute and thus affect qualitative and quantitative results. In this paper, sonolytic reactions of phenanthrene in common organic extraction solutions were examined using a 20kHz ultrasonic probe under conditions commonly used for ultrasonic extraction. Extraction parameters including phenanthrene concentration, solvent type, pulse length, and sonication time were investigated. Hexane:acetone (1:1 V/V) resulted in less phenanthrene degradation than dichloromethane (DCM):acetone (1:1 V/V). Initial solute concentration, length of sonication time, and solvent type affected the degradation of phenanthrene. Reaction byproducts including methylphenanthrene and methylnaphthalene detected after sonication indicate that phenanthrene reacts by both direct pyrolysis and reaction with methyl or ethyl radicals formed from solvent pyrolysis" |
| Keywords: | Organic Chemicals/*chemistry Phenanthrenes/*chemistry Solutions Ultrasonics; |
| Notes: | "MedlineSun, Ping Weavers, Linda K eng Research Support, Non-U.S. Gov't England 2006/07/11 Chemosphere. 2006 Dec; 65(11):2268-74. doi: 10.1016/j.chemosphere.2006.05.029. Epub 2006 Jul 7" |
