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Angew Chem Int Ed Engl

Title:		Single-Layered Hybrid Materials Based on 1D Associated Metalorganic Nanoribbons for Controlled Release of Pheromones
Author(s):		Moreno JM; Navarro I; Diaz U; Primo J; Corma A;
Address:		"Instituto de Tecnologia Quimica, Universitat Politecnica de Valencia-Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s/n, 46022, Valencia, Spain. Centro de Ecologia Quimica Agricola, Universidad Politecnica de Valencia, Edificio 6C, 5aplanta, Avenida de los naranjos s/n, 46022, Valencia, Spain. Instituto de Tecnologia Quimica, Universitat Politecnica de Valencia-Consejo Superior de Investigaciones Cientificas, Avenida de los Naranjos s/n, 46022, Valencia, Spain. acorma@itq.upv.es"
Journal Title:		Angew Chem Int Ed Engl
Year:		2016
Volume:		20160722
Issue:		37
Page Number:		11026 - 11030
DOI:		10.1002/anie.201602215
ISSN/ISBN:		1521-3773 (Electronic) 1433-7851 (Print) 1433-7851 (Linking)
Abstract:		"A new family of stable layered organic-inorganic materials has been prepared, in one-step solvothermal process. They are based on an ordered nickel cluster-type nanoribbons separated from each other by specific alkyl (heptyl- or dodecyl-) arylic mono-carboxylate moieties acting as molecular spacers, perpendicular to the 1D inorganic chains. These organic spacers contain hydrocarbon tails with different length which control the separation level between inorganic 1D sub-units, inhibiting the 3D growth of conventional DUT-8-type metal-organic frameworks (MOFs). The lamellar nature of the materials formed was studied and confirmed by different characterization techniques, showing the structural location of individual organic and inorganic building units. They have been successfully used as a long-lasting biodegradable and water-proof materials for controlled release of chemicals, such as pheromones for sustainable treatment of insect plagues"
Keywords:		*Drug Liberation Kinetics Metal-Organic Frameworks/chemical synthesis/*chemistry Nanostructures/*chemistry Nickel/*chemistry Particle Size Pheromones/*analysis/*chemistry X-Ray Diffraction controlled release layered structures metalorganic nanosheets orga;
Notes:		"MedlineMoreno, Jose Maria Navarro, Ismael Diaz, Urbano Primo, Jaime Corma, Avelino eng Research Support, Non-U.S. Gov't Germany 2016/07/23 Angew Chem Int Ed Engl. 2016 Sep 5; 55(37):11026-30. doi: 10.1002/anie.201602215. Epub 2016 Jul 22"