| Title: | Secondary organic aerosol from limona ketone: insights into terpene ozonolysis via synthesis of key intermediates |
| Author(s): | Donahue NM; Tischuk JE; Marquis BJ; Huff Hartz KE; |
| Address: | "Center for Atmospheric Particle Studies, Carnegie Mellon University, USA" |
| ISSN/ISBN: | 1463-9076 (Print) 1463-9076 (Linking) |
| Abstract: | "Limona ketone was synthesized to explore the secondary organic aerosol (SOA) formation mechanism from limonene ozonolysis and also to test group-additivity concepts describing the volatility distribution of ozonolysis products from similar precursors. Limona ketone SOA production is indistinguishable from alpha-pinene, confirming the expected similarity. However, limona ketone SOA production is significantly less intense than limonene SOA production. The very low vapor pressure of limonene ozonolysis products is consistent with full oxidation of both double bonds in limonene and furthermore with production of products other than ketones after oxidation of the exo double bond in limonene. Mass-balance constraints confirm that ketone products from exo double-bond ozonolysis have a minimal contribution to the ultimate product yield. These results serve as the foundation for an emerging framework to describe the effect on volatility of successive generations of organic compounds in the atmosphere" |
| Notes: | "PubMed-not-MEDLINEDonahue, Neil M Tischuk, Joshua E Marquis, Bryce J Huff Hartz, Kara E eng Research Support, U.S. Gov't, Non-P.H.S. England 2007/06/07 Phys Chem Chem Phys. 2007 Jun 21; 9(23):2991-8. doi: 10.1039/b701333g. Epub 2007 Apr 17" |
