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J Am Chem Soc


Title:Diverse chemiresistors based upon covalently modified multiwalled carbon nanotubes
Author(s):Wang F; Swager TM;
Address:"Department of Materials Science, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA"
Journal Title:J Am Chem Soc
Year:2011
Volume:20110630
Issue:29
Page Number:11181 - 11193
DOI: 10.1021/ja201860g
ISSN/ISBN:1520-5126 (Electronic) 0002-7863 (Linking)
Abstract:"A diverse array of multiwalled carbon nanotube (MWCNT) sensory materials have been synthesized and used to create sensors capable of identifying volatile organic compounds (VOCs) on the basis of their functional groups. Functionalized MWCNTs with a series of cross-sensitive recognition groups were successfully synthesized via zwitterionic and post-transformation synthetic procedures. The incorporated chemical functional groups on MWCNT surfaces introduced greatly increased sensitivity and selectivity to the targeted analytes. The distinct response pattern of each chemical was subjected to statistical treatments, which led to a clear separation and accurate identification of 100% of the VOCs. These results demonstrate that covalent functionalized MWCNT-based sensor arrays are a promising approach for low-cost, real time detection and identification of VOCs"
Keywords:"*Electric Conductivity Electrochemical Techniques/instrumentation Equipment Design Microarray Analysis/*instrumentation Nanotubes, Carbon/*chemistry/ultrastructure Sensitivity and Specificity Volatile Organic Compounds/*analysis;"
Notes:"MedlineWang, Fei Swager, Timothy M eng Evaluation Study Research Support, U.S. Gov't, Non-P.H.S. 2011/07/02 J Am Chem Soc. 2011 Jul 27; 133(29):11181-93. doi: 10.1021/ja201860g. Epub 2011 Jun 30"

 
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