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Dalton Trans

Title:		"Synthesis and characterization of bis (acetylacetonato kappa-O, O') [zinc(ii)/copper(ii)] hybrid organic-inorganic complexes as solid metal organic precursors"
Author(s):		Rooydell R; Wang RC; Brahma S; Ebrahimzadeh F; Liu CP;
Address:		"Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Tainan, Taiwan. cpliu@mail.ncku.edu.tw"
Journal Title:		Dalton Trans
Year:		2015
Volume:		44
Issue:		17
Page Number:		7982 - 7990
DOI:		10.1039/c5dt00808e
ISSN/ISBN:		1477-9234 (Electronic) 1477-9226 (Linking)
Abstract:		"We have synthesized novel metal organic hybrid mixed compounds of bis (acetylacetonato kappa-O, O') [zinc(ii)/copper(ii)]. Taking C10H14O4Zn0.7Cu0.3 (Z0.7C0.3AA) as an example, the crystals are composed of Z0.7C0.3AA units and uncoordinated water molecules. Single-crystal X-ray diffraction results show that the complex Z0.7C0.3AA crystallizes in the monoclinic system, space group P21/n. The unit cell dimensions are a = 10.329(4) A, b = 4.6947(18) A, and c = 11.369(4) A; the angles are alpha = 90 degrees , beta = 91.881(6) degrees , and gamma = 90 degrees , the volume is 551.0(4) A(3), and Z = 2. In this process, the M(ii) ions of Zn and Cu mix and occupy the centers of symmetrical structural units, which are coordinated to two ligands. The measured bond lengths and angles of O-M-O vary with the ratio of metal species over the entire series of the complexes synthesized. The chemistry of the as-synthesized compounds has been characterized using infrared spectroscopy, mass spectroscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy analysis, and the morphology of the products has been characterized using scanning electron microscopy. The thermal decomposition of the Z0.7C0.3AA composites measured by thermogravimetric analysis suggests that these complexes are volatile. The thermal characteristics of these complexes make them attractive precursors for metal organic chemical vapor deposition"
Keywords:
Notes:		"PubMed-not-MEDLINERooydell, Reza Wang, Ruey-Chi Brahma, Sanjaya Ebrahimzadeh, Farzaneh Liu, Chuan-Pu eng England 2015/04/01 Dalton Trans. 2015 May 7; 44(17):7982-90. doi: 10.1039/c5dt00808e"