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Bioorg Med Chem


Title:"Pheromone syntheses: a tropical approach. Enantioselective synthesis of the (2R,6S,10S) and (2S,6S,10S) isomers of methyl 2,6,10-trimethyldodecanoate"
Author(s):Ferreira JT; Zarbin PH;
Address:"Laboratorio de Sintese de Produtos Naturais, Departamento de Quimica, Universidade Federal de Sao Carlos, Sao Carlos-SP, Brazil"
Journal Title:Bioorg Med Chem
Year:1996
Volume:4
Issue:3
Page Number:381 - 388
DOI: 10.1016/0968-0896(96)00015-6
ISSN/ISBN:0968-0896 (Print) 0968-0896 (Linking)
Abstract:"The enantioselective syntheses of two stereoisomers, (2R,6S,10S) and (2S,6S,10S), of methyl 2,6,10-trimethyldodecanote, out of eight possible isomers, are described , employing the stereoselective hydroboration of (-)-isopulegol (2) and (+)-neo-isopulegol (2a) as the key reaction"
Keywords:"Animals Insecta/*chemistry Laurates/*chemical synthesis Magnetic Resonance Spectroscopy Male Sex Attractants/*chemical synthesis Spectrophotometry, Infrared Stereoisomerism;"
Notes:"MedlineFerreira, J T Zarbin, P H eng Research Support, Non-U.S. Gov't England 1996/03/01 Bioorg Med Chem. 1996 Mar; 4(3):381-8. doi: 10.1016/0968-0896(96)00015-6"

 
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