| Title: | "Enantiomer separation of 1,4-sulfanylalcohols by conventional and low-temperature gas chromatography" |
| Author(s): | Filippi JJ; Fernandez X; Loiseau AM; Lizzani-Cuvelier L; Meierhenrich UJ; |
| Address: | "Universitat Hohenheim, Bioanorganische Chemie, Stuttgart, Germany" |
| ISSN/ISBN: | 0899-0042 (Print) 0899-0042 (Linking) |
| Abstract: | "Since 1990, the family of organosulfur molecules has assumed increasing importance in pheromone, flavour, and fragrance chemistry. Depending on the constitution of the functional groups, various volatile sulfur-containing compounds are chiral. However, hitherto it has been impossible to study the chirality of 1,4-sulfanylalcohols, since no adequate enantioselective analytical technique has been available. Here we report on the enantiomer separation of ten volatile 1,4-sulfanylalcohol homologues by applying an heptakis(6-O-tert-butyldimethylsilyl-2,3-di-O-methyl)-beta-cyclodextrin phase, involving in some cases the use of a low-temperature gas chromatographic (ltGC) technique. The results are expected to open research potential on the asymmetry of volatile organosulfur molecules, particularly in the fields of pheromone, flavour, and fragrance research" |
| Keywords: | "Alcohols/*analysis/chemistry/classification/*isolation & purification Chromatography, Gas/*methods *Cold Temperature Flavoring Agents/*analysis/chemistry/classification/*isolation & purification Molecular Structure Stereoisomerism;" |
| Notes: | "MedlineFilippi, Jean-Jacques Fernandez, Xavier Loiseau, Andre-Michel Lizzani-Cuvelier, Louisette Meierhenrich, Uwe J eng Research Support, Non-U.S. Gov't 2006/04/28 Chirality. 2006 Aug; 18(7):558-61. doi: 10.1002/chir.20288" |
