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ChemSusChem


Title:"Characterization of atmospheric particulate: relationship between chemical composition, size, and emission source"
Author(s):Di Tullio A; Reale S; Ciammola M; Arrizza L; Picozzi P; De Angelis F;
Address:"Dipartimento di Chimica, Ingegneria Chimica e Materiali, Universita dell'Aquila, Via Vetoio Coppito II-67100, Coppito L'Aquila, Italy"
Journal Title:ChemSusChem
Year:2008
Volume:1
Issue:1-Feb
Page Number:110 - 117
DOI: 10.1002/cssc.200700056
ISSN/ISBN:1864-5631 (Print) 1864-5631 (Linking)
Abstract:"Physicochemical characterization of particulate matter fractionated into eight samples by size from 10 to 0.43 microm was performed by HS-SPME/GC-MS for the organic (semi-)volatile components and SEM X-ray microanalysis (SEM/EDX) for analysis of the elemental composition. The HS-SPME technique was shown to be efficient with respect to requiring an extremely low amount of material, being selective and clean and avoiding use of any solvents. Particulate matter was collected at four sites characterized by particular environmental locations and different pollution levels around the city of L'Aquila in central Italy. The results reveal a tight correlation between the particle composition, size, and the emission source. The analyses show also that the finer the particle, the higher its content of elemental carbon and organic compounds. Well-known carcinogens such as PAHs were detected among the identified organic compounds from both the rural and highly polluted sites"
Keywords:"Atmosphere/*chemistry Electron Probe Microanalysis Health Inorganic Chemicals/chemistry Microscopy, Electron, Scanning Organic Chemicals/chemistry *Particle Size Particulate Matter/*analysis/*chemistry/toxicity Vehicle Emissions/*analysis Volatilization;"
Notes:"MedlineDi Tullio, Alessandra Reale, Samantha Ciammola, Margherita Arrizza, Lorenzo Picozzi, Pietro De Angelis, Francesco eng Research Support, Non-U.S. Gov't Germany 2008/07/09 ChemSusChem. 2008; 1(1-2):110-7. doi: 10.1002/cssc.200700056"

 
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