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ACS Omega


Title:"Study on Thermal Risk of Coal-Based Activated Carbon after Adsorbing Acetone, Cyclohexane, and Butyl Acetate"
Author(s):Wang L; Fan Q; Wang Y; Xu Y; Li Y; Zheng Y; Feng X; Zhang K;
Address:"School of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China. Collaborative Innovation Center for Coal Safety Production & High-Efficient-Clean Utilization for Coal by Provincial and Ministerial Co-Construction, Jiaozuo 454003, China. State Key Laboratory Cultivation Base for Gas Geology and Gas Control in Henan Polytechnic University, Jiaozuo 454003, China. School of Computer Science and Technology, Henan Polytechnic University, Jiaozuo 454003, China. Department of System Safety Engineering, Nagaoka University of Technology, 1603-1 Kamitomioka-machi, Nagaoka-shi, Niigata 940-2188, Japan"
Journal Title:ACS Omega
Year:2023
Volume:20230911
Issue:37
Page Number:33883 - 33890
DOI: 10.1021/acsomega.3c04577
ISSN/ISBN:2470-1343 (Electronic) 2470-1343 (Linking)
Abstract:"Combustion and explosion accidents of the mixture may occur after the adsorption of volatile organic compounds (VOCs) by coal-based activated carbon (CBAC). It is of great significance to explore the oxidation and combustion performance of CBAC before and after adsorbing VOCs in order to prevent the reoccurrence of fire and explosion. Based on the CBAC sample commonly used in industrial production, three types of CBAC samples after adsorbing VOCs, i.e., acetone, cyclohexane, and butyl acetate, were prepared. The oxidation and combustion characteristics of the samples before and after adsorbing VOCs are measured and analyzed by thermal analyzer and cone calorimeter. Thermal analysis results indicate that during the oxidation process, the VOCs in the adsorbed samples will burn in the early stage, generating amounts of heat which may accelerate the oxidation and combustion of CBAC. According to the combustion performance experiments by cone calorimeter, it is also found that the combustion rate of CBAC after adsorbing VOCs is significantly enhanced. The time to ignition is shortened, the heat release rate becomes larger, and the time to reach the peak of heat release rate is significantly moved forward. In addition, the CO yield of the adsorbed sample is significantly improved. In general, VOC adsorption in CBAC can promote oxidation reactions and may result in an enhanced combustibility of CBAC"
Keywords:
Notes:"PubMed-not-MEDLINEWang, Lanyun Fan, Qinghui Wang, Yan Xu, Yongliang Li, Yao Zheng, Yanmei Feng, Xiaodong Zhang, Kun eng 2023/09/25 ACS Omega. 2023 Sep 11; 8(37):33883-33890. doi: 10.1021/acsomega.3c04577. eCollection 2023 Sep 19"

 
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