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Huan Jing Ke Xue

Title:		[CoCuMnOx Photocatalyzed Oxidation of Multi-component VOCs and Kinetic Analysis]
Author(s):		Meng HL; Bo LL; Liu JD; Gao B; Feng QQ; Tan N; Xie S;
Address:
Journal Title:		Huan Jing Ke Xue
Year:		2016
Volume:		37
Issue:		5
Page Number:		1670 - 1676
DOI:
ISSN/ISBN:		0250-3301 (Print) 0250-3301 (Linking)
Abstract:		"Solar energy absorption coating CoCuMnOx was prepared by co-precipitation method and applied to photodegrade multi- component VOCs including toluene, ethyl acetate and acetone under visible light irradiation. The photocatalytic oxidation performance of toluene, ethyl acetate and acetone was analyzed and reaction kinetics of VOCs were investigated synchronously. The research indicated that removal rates of single-component toluene, ethyl acetate and acetone were 57%, 62% and 58% respectively under conditions of 400 mg . m(-)(3) initial concentration, 120 mm illumination distance, 1 g/350 cm(2) dosage of CoCuMnOx and 6 h of irradiation time by 100 W tungsten halogen lamp. Due to the competition among different VOCs, removal efficiencies in three-component mixture were reduced by 5%-26% as compared with single VOC. Degradation processes of single-component VOC and three-component VOCs both fitted pseudo first order reaction kinetics, and kinetic constants of toluene, ethyl acetate and acetone were 0.002, 0.002 8 and 0.002 33 min(-)(1) respectively under single-component condition. Reaction rates of VOCs in three-component mixture were 0.49-0.88 times of single components"
Keywords:		Acetates/chemistry Acetone/chemistry Kinetics Light *Oxidation-Reduction *Photolysis Toluene/chemistry Volatile Organic Compounds/*chemistry;
Notes:		"MedlineMeng, Hai-long Bo, Long-li Liu, Jia-dong Gao, Bo Feng, Qi-qi Tan, Na Xie, Shuai chi China 2016/08/11 Huan Jing Ke Xue. 2016 May 15; 37(5):1670-6"