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Org Lett

Title:		Efficient preparation of terminal conjugated dienes by coupling of dienol phosphates with grignard reagents under iron catalysis
Author(s):		Cahiez G; Habiak V; Gager O;
Address:		"Laboratoire de Synthese Organique Selective et de Chimie Organometallique (SOSCO), UMR 8123 CNRS-UCP-ESCOM, 5, Mail Gay-Lussac, Neuville sur Oise, Cergy-Pontoise Cedex, France. gerard.cahiez@chim.u-cergy.fr"
Journal Title:		Org Lett
Year:		2008
Volume:		20080514
Issue:		12
Page Number:		2389 - 2392
DOI:		10.1021/ol800816f
ISSN/ISBN:		1523-7060 (Print) 1523-7052 (Linking)
Abstract:		An efficient new route to prepare stereoselectively terminal conjugated dienes by coupling Grignard reagents and dienol phosphates in the presence of Fe(acac)3 is described. The synthetic utility of this new iron-catalyzed procedure is illustrated by the synthesis of the pheromone of Diparopsis castanea according to a very expeditious strategy
Keywords:		Animals Catalysis Indicators and Reagents Iron/*chemistry Molecular Structure Moths/chemistry Pheromones/*biosynthesis Polyenes/*chemical synthesis/*chemistry Stereoisomerism;
Notes:		"MedlineCahiez, Gerard Habiak, Vanessa Gager, Olivier eng Research Support, Non-U.S. Gov't 2008/05/15 Org Lett. 2008 Jun 19; 10(12):2389-92. doi: 10.1021/ol800816f. Epub 2008 May 14"