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J Nat Prod


Title:"Identification, syntheses, and characterization of the geometric isomers of 9,11-hexadecadienal from female pheromone glands of the sugar cane borer Diatraea saccharalis"
Author(s):Santangelo EM; Coracini M; Witzgall P; Correa AG; Unelius CR;
Address:"Department of Chemistry, Organic Chemistry, The Royal Institute of Technology, SE-10044 Stockholm, Sweden"
Journal Title:J Nat Prod
Year:2002
Volume:65
Issue:6
Page Number:909 - 915
DOI: 10.1021/np010551i
ISSN/ISBN:0163-3864 (Print) 0163-3864 (Linking)
Abstract:"Chemical analysis of the pheromone glands of the sugar cane borer Diatraea saccharalis has shown the presence of the four geometric isomers of 9,11-hexadecadienal (1-4), in addition to hexadecanal and (Z)-hexadec-11-enal. We here report the syntheses and characterization of compounds 1-4. One starting material, 9-decen-1-ol, has been used to obtain all of them via divergent synthetic routes"
Keywords:"Aldehydes/*chemical synthesis/*chemistry Alkadienes/*chemical synthesis/*chemistry Animals Brazil Female Lepidoptera/*chemistry Mass Spectrometry Nuclear Magnetic Resonance, Biomolecular Pheromones/*chemical synthesis/*chemistry Stereoisomerism;"
Notes:"MedlineSantangelo, Ellen M Coracini, Myrian Witzgall, Peter Correa, Arlene G Unelius, C Rikard eng Research Support, Non-U.S. Gov't 2002/06/29 J Nat Prod. 2002 Jun; 65(6):909-15. doi: 10.1021/np010551i"

 
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