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J Nanosci Nanotechnol


Title:Nano-Ag-Nafion modified Pt electrode for oxidation of volatile organic compounds: an electrochemical study
Author(s):Muthuraman G; Chung SJ; Moon IS;
Address:"Department of Chemical Engineering, Sunchon National University, #413 Jungangno, Suncheon 540-742, Jeollanam-do, Republic of Korea"
Journal Title:J Nanosci Nanotechnol
Year:2011
Volume:11
Issue:8
Page Number:7399 - 7403
DOI: 10.1166/jnn.2011.4808
ISSN/ISBN:1533-4880 (Print) 1533-4880 (Linking)
Abstract:"In this work, we describe Nano-Ag-Nafion coated pt electrode for oxidation of volatile organic compound (VOC), here acetaldehyde. Electrochemically synthesized Nano-Ag-Nafion film on Pt was analyzed by electrochemically in various electrolyte solutions like nitric acid, sulfuric acid, potassium nitrate, and potassium hydroxide for its stability. High stability of Nano-Ag-Nafion film appeared in potassium hydroxide medium among electrolyte solutions studied. Electrocatalysis of acetaldehyde was occurred only in acid and neutral medium. A catalytic oxidative peak during cathodic voltammetric reduction scan was observed at 1.75 V, which, unusual redox behavior, follows EC' reaction path way between electrogenerated Ag(II) and acetaldehyde. For Nano-Ag potential applicability, a calibration plot was drawn from various concentration range of acetaldehyde to check the maximum concentration level of acetaldehyde degradation in air"
Keywords:
Notes:"PubMed-not-MEDLINEMuthuraman, G Chung, Sang Joon Moon, Il Shik eng 2011/11/23 J Nanosci Nanotechnol. 2011 Aug; 11(8):7399-403. doi: 10.1166/jnn.2011.4808"

 
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