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Chemistry

Title:		The Future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water
Author(s):		Garcia-Alvarez J; Hevia E; Capriati V;
Address:		"Laboratorio de Compuestos Organometalicos y Catalisis, Departamento de Quimica Organica e Inorganica (IUQOEM), Instituto, Universitario de Quimica Organometalica 'Enrique Moles', Facultad de Quimica, Universidad de Oviedo, 33071, Oviedo, Spain. WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, G1 1XL, UK. Dipartimento di Farmacia-Scienze del Farmaco, Universita di Bari 'Aldo Moro', Consorzio C.I.N.M.P.I.S., Via E. Orabona, 4, 70125, Bari, Italy"
Journal Title:		Chemistry
Year:		2018
Volume:		20180920
Issue:		56
Page Number:		14854 - 14863
DOI:		10.1002/chem.201802873
ISSN/ISBN:		1521-3765 (Electronic) 0947-6539 (Linking)
Abstract:		"There is a strong imperative to reduce the release of volatile organic compounds (VOCs) into the environment, and many efforts are currently being made to replace conventional hazardous VOCs in favour of safe, green and bio-renewable reaction media that are not based on crude petroleum. Recent ground-breaking studies from a few laboratories worldwide have shown that both Grignard and (functionalised) organolithium reagents, traditionally handled under strict exclusion of air and humidity and in anhydrous VOCs, can smoothly promote both nucleophilic additions to unsaturated substrates and nucleophilic substitutions in water and other bio-based solvents (glycerol, deep eutectic solvents), competitively with protonolysis, at room temperature and under air. The chemistry of polar organometallics in the above protic media is a complex phenomenon influenced by several factors, and understanding its foundational character is stimulating in the perspective of the development of a sustainable organometallic chemistry"
Keywords:		deep eutectic solvents organometallic chemistry solvent effects sustainable chemistry water;
Notes:		"PubMed-not-MEDLINEGarcia-Alvarez, Joaquin Hevia, Eva Capriati, Vito eng Capriati005057Prin15/Universita degli Studi di Bari Aldo Moro/ EP/N011384/1/Engineering and Physical Sciences Research Council/ CTQ2014-51912-REDC, CTQ2016-75986-P/MINECO of Spain/ GRUPIN14-006/Gobierno del Principado de Asturias/ Fundacion BBVA/ Germany 2018/06/20 Chemistry. 2018 Oct 9; 24(56):14854-14863. doi: 10.1002/chem.201802873. Epub 2018 Sep 20"