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ACS Omega

Title:		Stereoselective Synthesis of Homofarnesenes: Establishment of an Efficient Method for the Stereoselective Preparation of Acyclic Tetrasubstituted Olefins
Author(s):		Yin W; Liang W; Guo L; Lei J; Qiu FG;
Address:		"Department of Chemistry, School of Wuhan University of Technology, 122 Luo-Shi Road, Wuhan 430070, China. University of the Chinese Academy of Sciences and Guangzhou Institute of Biomedicine and Health, Chinese Academy of Sciences, 190 Kaiyuan Ave, Guangzhou 510530, China"
Journal Title:		ACS Omega
Year:		2018
Volume:		20180426
Issue:		4
Page Number:		4551 - 4556
DOI:		10.1021/acsomega.8b00439
ISSN/ISBN:		2470-1343 (Electronic) 2470-1343 (Linking)
Abstract:		"A new method for the stereoselective synthesis of tetrasubstituted olefins is described. beta-Ketophosphonates are alkylated via conventional methods, and a Grignard reagent is used to diastereoselectively add to the carbonyl group of the resulting intermediates. The elimination of hydroxyl phosphonates yielded the desired tetrasubstituted olefins in a stereoselective manner. Thus, homofarnesenes of fire ant trail pheromones have been synthesized efficiently using this strategy"
Keywords:
Notes:		"PubMed-not-MEDLINEYin, Wenhao Liang, Weihong Guo, Liping Lei, Jiaheng Qiu, Fayang G eng 2018/04/26 ACS Omega. 2018 Apr 26; 3(4):4551-4556. doi: 10.1021/acsomega.8b00439. eCollection 2018 Apr 30"