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Chem Biodivers


Title:The Tracing of VOC Composition of Acacia Honey During Ripening Stages by Comprehensive Two-Dimensional Gas Chromatography
Author(s):Vyviurska O; Chlebo R; Pysarevska S; Spanik I;
Address:"Institute of Analytical Chemistry, Slovak University of Technology, SK-81237, Bratislava, Slovakia. Department of Poultry Science and Small Animal Husbandry, Slovak Agricultural University, 94976, Nitra, Slovakia. Department of Life Safety, Ivan Franko National University, 79000, Lviv, Ukraine. Institute of Analytical Chemistry, Slovak University of Technology, SK-81237, Bratislava, Slovakia. ivan.spanik@stuba.sk"
Journal Title:Chem Biodivers
Year:2016
Volume:13
Issue:10
Page Number:1316 - 1325
DOI: 10.1002/cbdv.201600056
ISSN/ISBN:1612-1880 (Electronic) 1612-1872 (Linking)
Abstract:"In this study, VOC profiles of acacia flowers and honey samples at different processing stages and related comb wax samples were studied using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry. It was found that some monoterpene compounds like alpha-pinene, myrcene, cis-beta-ocimene, and 4-terpineol were common for acacia flower and all acacia honey samples, and the presence of verbenone and ocimene was first established in acacia honey. The most enriched VOC profile was obtained for raw honey before cell capping, where the final composition of lactones was achieved. On the contrary, number of alcohols, esters, and variety of terpenes, as well as their concentration in the honey samples decrease through ripening processes. Strained honey was characterized by the absence of camphor, alpha-bisabolol, and 3-carene, while isophorone and hexanoic acid were identified only in this type of honey. The composition of final VOC profile of honey was also influenced by the age of comb wax. The additional aromatic and lactone compounds, e.g., phenol, 1-phenylethanol, delta-hexalactone, and gamma-heptalactone were observed for honey maturated in old dark comb wax"
Keywords:"Acacia/*chemistry Chromatography, Gas Flowers/*chemistry Honey/*analysis Mass Spectrometry Time Factors Volatile Organic Compounds/*analysis/*chemistry Acacia flower Acacia honey Comprehensive two-dimensional gas chromatography Ripening Volatile profile;"
Notes:"MedlineVyviurska, Olga Chlebo, Robert Pysarevska, Solomiya Spanik, Ivan eng Switzerland 2016/07/28 Chem Biodivers. 2016 Oct; 13(10):1316-1325. doi: 10.1002/cbdv.201600056"

 
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