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Biosci Biotechnol Biochem


Title:"Synthesis of (1R,7Z)-1-methyl-7-hexadecenyl acetate, the female sex pheromone of the honey locust gall midge"
Author(s):Shikichi Y; Mori K;
Address:"Photosensitive Materials Research Center, Toyo Gosei Co, Ltd, Inzai, Chiba, Japan"
Journal Title:Biosci Biotechnol Biochem
Year:2012
Volume:20120707
Issue:7
Page Number:1419 - 1421
DOI: 10.1271/bbb.120265
ISSN/ISBN:1347-6947 (Electronic) 0916-8451 (Linking)
Abstract:"(1R,7Z)-1-Methyl-7-hexadecenyl acetate (1), the female sex pheromone of the honey locust gall midge (Dasineura gleditchiae), was synthesized from 6-hepten-1-ol in an 8.9% overall yield (eight steps). Hydrolytic kinetic resolution of (+/-)-1,2-epoxy-8-heptadecyne was the key step in the synthesis"
Keywords:Acetates/*chemical synthesis Animals Chironomidae/*chemistry/physiology Fatty Alcohols/*chemistry Female Gas Chromatography-Mass Spectrometry Magnetic Resonance Spectroscopy Sex Attractants/*chemical synthesis Stereoisomerism;
Notes:"MedlineShikichi, Yasumasa Mori, Kenji eng England 2012/07/13 Biosci Biotechnol Biochem. 2012; 76(7):1419-21. doi: 10.1271/bbb.120265. Epub 2012 Jul 7"

 
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