Title: | "Synthesis of the sex pheromone of the citrus mealybug, Pseudococcus cryptus" |
Author(s): | Nakahata T; Itagaki N; Arai T; Sugie H; Kuwahara S; |
Address: | "Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University, Sendai, Japan" |
Journal Title: | Biosci Biotechnol Biochem |
ISSN/ISBN: | 0916-8451 (Print) 0916-8451 (Linking) |
Abstract: | "The sex pheromone of the citrus mealybug (Pseudococcus cryptus), [(1R,3R)-3-isopropenyl-2,2-dimethylcyclobutyl]methyl 3-methyl-3-butenoate, was synthesized from (+)-alpha-pinene in five operational steps in a 43% overall yield. The synthetic pheromone was identical with the natural pheromone in (1)H-NMR and mass spectroscopic properties, and showed almost the same pheromonal activity as the natural pheromone" |
Keywords: | Animals Bicyclic Monoterpenes Butyrates/*chemical synthesis Cyclobutanes/*chemical synthesis Hemiptera/*metabolism Monoterpenes/chemical synthesis/*chemistry Sex Attractants/chemical synthesis/*chemistry; |
Notes: | "MedlineNakahata, Takashi Itagaki, Noriaki Arai, Tomonori Sugie, Hajime Kuwahara, Shigefumi eng Research Support, Non-U.S. Gov't England 2004/01/20 Biosci Biotechnol Biochem. 2003 Dec; 67(12):2627-31. doi: 10.1271/bbb.67.2627" |