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Talanta

Title:		Simultaneous determination of 76 micropollutants in water samples by headspace solid phase microextraction and gas chromatography-mass spectrometry
Author(s):		Martinez C; Ramirez N; Gomez V; Pocurull E; Borrull F;
Address:		"Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili, Marcel.li Domingo s/n, Sescelades Campus, 43007 Tarragona, Spain"
Journal Title:		Talanta
Year:		2013
Volume:		20130731
Issue:
Page Number:		937 - 945
DOI:		10.1016/j.talanta.2013.07.055
ISSN/ISBN:		1873-3573 (Electronic) 0039-9140 (Linking)
Abstract:		"This study focuses on the development of an analytical method based on headspace solid phase microextraction (HS-SPME) and gas chromatography-mass spectrometry (GC-MS) for the simultaneous determination of 76 micropollutants in water samples. The selected micropollutants include volatile organic compounds (VOCs) (e.g. chlorobenzenes, chloroalkanes), endocrine disrupting compounds (EDCs) (e.g. bisphenol A and tributyl phosphate), odour compounds (e.g. limonene, phenol), fragrance allergens (e.g. geraniol, eugenol) and some pesticides (e.g. heptachlor, terbutryn). The experimental conditions affecting their extraction, such as the type of fibre, temperature and time of extraction, sample volume and ionic strength of the samples were optimized using HS-SPME. The method showed good linear range, reproducibility between days, repeatability and low detection limits (at ng L(-1) levels). The validated method has been applied to determine the target organic micropollutants in aqueous samples from different experimental research units of surface water, sea water, waste water and those effluents of advance membrane treatments. The optimized method showed good performance in the different types of samples studied. The analysis revealed the presence of several micropollutants at concentrations between 20 and 5000 mug L(-1), such as ethylbenzene, o-xylene, p-isopropilbenzene, D-limonene, citral and isoeugenol, due to the fact that these species are commonly used in domestic and industrial applications"
Keywords:		Allergens/isolation & purification Endocrine Disruptors/isolation & purification Fresh Water/*chemistry Gas Chromatography-Mass Spectrometry Humans Limit of Detection Pesticides/isolation & purification Reproducibility of Results Seawater/*chemistry Solid;
Notes:		"MedlineMartinez, C Ramirez, N Gomez, V Pocurull, E Borrull, F eng Research Support, Non-U.S. Gov't Netherlands 2013/10/24 Talanta. 2013 Nov 15; 116:937-45. doi: 10.1016/j.talanta.2013.07.055. Epub 2013 Jul 31"