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Anal Bioanal Chem

Title:		Solid-phase microextraction Arrow combined with comprehensive two-dimensional gas chromatography-mass spectrometry for the elucidation of the volatile composition of honey samples
Author(s):		Manousi N; Kalogiouri N; Ferracane A; Zachariadis GA; Samanidou VF; Tranchida PQ; Mondello L; Rosenberg E;
Address:		"Laboratory of Analytical Chemistry, Department of Chemistry, Aristotle University of Thessaloniki, 54124, Thessaloniki, Greece. Institute of Chemical Technology and Analytics, Vienna University of Technology, Getreidemarkt 9/164, 1060, Vienna, Austria. Institute of Chemical Technology and Analytics, Vienna University of Technology, Getreidemarkt 9/164, 1060, Vienna, Austria. aferracane@unime.it. Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Messina, Italy. aferracane@unime.it. Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Messina, Italy. Chromaleont S.R.L., c/o Department of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Messina, Italy. Department of Sciences and Technologies for Human and Environment, University Campus Bio-Medico of Rome, Rome, Italy"
Journal Title:		Anal Bioanal Chem
Year:		2023
Volume:		20230111
Issue:		13
Page Number:		2547 - 2560
DOI:		10.1007/s00216-023-04513-0
ISSN/ISBN:		1618-2650 (Electronic) 1618-2642 (Linking)
Abstract:		"In this work, a solid-phase microextraction (SPME) Arrow method combined with comprehensive two-dimensional gas chromatography-mass spectrometry (GC x GC-MS) was developed for the elucidation of the volatile composition of honey samples. The sample preparation protocol was optimized to ensure high extraction efficiency of the volatile organic compounds (VOCs) which are directly associated with the organoleptic properties of honey and its acceptance by the consumers. Following its optimization, SPME Arrow was compared to conventional SPME in terms of sensitivity, precision, and number of extracted VOCs. The utilization of SPME Arrow fibers enabled the determination of 203, 147, and 149 compounds in honeydew honey, flower honey, and pine honey, respectively, while a significantly lower number of compounds (124, 94, and 111 for honeydew honey, flower honey, and pine honey, respectively) was determined using conventional SPME. At the same time, the utilization of SPME Arrow resulted in enhanced sensitivity and precision. All things considered, SPME Arrow and GC x GC-MS can be considered as highly suitable for the elucidation of the volatile composition of complex food samples resulting in high sensitivity and separation efficiency"
Keywords:		Gas Chromatography-Mass Spectrometry/methods *Honey/analysis Solid Phase Microextraction/methods *Volatile Organic Compounds/analysis Comprehensive two-dimensional gas chromatography Honey Solid-phase microextraction Arrow Volatile organic compounds;
Notes:		"MedlineManousi, Natalia Kalogiouri, Natasa Ferracane, Antonio Zachariadis, George A Samanidou, Victoria F Tranchida, Peter Q Mondello, Luigi Rosenberg, Erwin eng Germany 2023/01/12 Anal Bioanal Chem. 2023 May; 415(13):2547-2560. doi: 10.1007/s00216-023-04513-0. Epub 2023 Jan 11"