| Title: | Photofunctional platinum complexes featuring N-heterocyclic carbene-based pincer ligands |
| Author(s): | Lin WJ; Naziruddin AR; Chen YH; Sun BJ; Chang AH; Wang WJ; Hwang WS; |
| Address: | "Department Department of Chemistry, National Dong Hwa University, Hualien 974, Taiwan (ROC), Fax:(+886) 3-8633570" |
| ISSN/ISBN: | 1861-471X (Electronic) 1861-471X (Linking) |
| Abstract: | "Photoactive platinum complexes of stoichiometry [Pt((R)CCC(R))L](0/+) (R = Me, nBu and L = -CN, -C identical withCPh, -N identical withCCH3, -Py, -CO) featuring pincer-type bis N-heterocyclic carbene (NHC) ligands ((R)CCC(R)) were synthesized. Organometallic syntheses of these complexes are facile and achievable through standard laboratory procedures. Control of intermolecular Pt?na?na?naPt interaction, pi-pi stacking, and emission tuning is achieved through suitable choice of the NHC-wingtip substituent (R) and the auxiliary ligand (L). Exposure to specific volatile organic compounds (VOCs) or mechanical grinding triggers changes in emission colors, which render these complexes photofunctional. Solid-state structures and photoluminescence results are described herein" |
| Keywords: | N-heterocyclic carbene complexes photoactive platinum complexes stimuli-responsive emission; |
| Notes: | "PubMed-not-MEDLINELin, Wan-Jung Naziruddin, Abbas Raja Chen, Yu-Hsuan Sun, Bian-Jian Chang, A Hsiu Hwa Wang, Wen-Jwu Hwang, Wen-Shu eng Germany 2015/02/11 Chem Asian J. 2015 Mar; 10(3):728-39. doi: 10.1002/asia.201403306. Epub 2015 Feb 6" |
