Title: | "Synthesis of grandisol, the sexual attracting insect pheromone" |
Address: | "Korea Research Institute of Bioscience and Biotechnology, Ochang 363-883, Korea. yskwak@kribb.re.kr" |
DOI: | 10.1007/s12272-011-0900-y |
ISSN/ISBN: | 1976-3786 (Electronic) 0253-6269 (Linking) |
Abstract: | "In this issue, Suh's group reported a new formal total synthesis of (+/-)-grandisol featuring a palladium-catalyzed 4-exo-trig cyclization. Grandisol's interesting cyclobutane structure has been a popular test model for various cyclization methods over the years. This report summarizes Suh's formal synthesis of grandisol along with a concise review of the four-membered ring cyclization strategies employed in the synthesis of grandisol" |
Keywords: | Animals Catalysis Cyclization Molecular Structure Palladium/chemistry Sex Attractants/*chemical synthesis/chemistry/pharmacology Stereoisomerism Terpenes/*chemical synthesis/chemistry/pharmacology *Weevils; |
Notes: | "MedlineKwak, Young-Shin Jeong, Byeong-Seon eng Korea (South) 2011/10/07 Arch Pharm Res. 2011 Sep; 34(9):1399-402. doi: 10.1007/s12272-011-0900-y" |