Title: | Use of biochar for the sorption of volatile organic compounds (VOCs) emitted from cattle manure |
Author(s): | Kaikiti K; Stylianou M; Agapiou A; |
Address: | "Department of Chemistry, University of Cyprus, P.O. Box 20537, CY-1678, Nicosia, Cyprus. Department of Chemistry, University of Cyprus, P.O. Box 20537, CY-1678, Nicosia, Cyprus. agapiou.agapios@ucy.ac.cy" |
Journal Title: | Environ Sci Pollut Res Int |
DOI: | 10.1007/s11356-020-09545-y |
ISSN/ISBN: | 1614-7499 (Electronic) 0944-1344 (Linking) |
Abstract: | "The ability of biochar to be used as filter or as additive for the adsorption of volatile organic compounds (VOCs) emitted from cattle manure is investigated. The employed biochar was produced from cattle manure after slow pyrolysis at 550 degrees C (under nitrogen). Towards this, in-house-made glass emission reactors were filled with fresh cattle manure samples and a thin layer of biochar (10% w/w) was placed on the top of the manure layer. The mixture was left for 24 h to equilibrate and air samples were collected from the headspace air. The samples were then analyzed using the headspace solid-phase micro-extraction gas chromatography-mass spectrometry (HS-SPME-GC-MS) method. Cattle manure emissions are considered unpleasant and odoriferous. The respective changes in the emitted cattle manure VOCs were reported; these included mainly reduction in sulfur- (thiols and sulfides) and oxygen-containing VOCs (alcohols, ketones, phenolics), showing a promising application of biochar for the removal of such compounds from manure wastes. Also, five VOCs were selected as sorbents for further laboratory studies: hexane, dimethyl trisulfide, phenol, p-cresol, and 2-methyl-3-pentanone. The results of cattle manure-derived biochar, revealed a reduction in their emitted concentrations (low ppb(v)). The present application highlights a straightforward example of cyclic economy, where a waste product is reused after being processed; its re-usage as odor adsorbent serves again the agriculture sector" |
Keywords: | Animals Cattle Charcoal Manure Solid Phase Microextraction *Volatile Organic Compounds Air quality Biochar Livestock Sorbents Waste; |
Notes: | "MedlineKaikiti, Kyriaki Stylianou, Marinos Agapiou, Agapios eng Germany 2020/06/20 Environ Sci Pollut Res Int. 2021 Nov; 28(42):59141-59149. doi: 10.1007/s11356-020-09545-y. Epub 2020 Jun 17" |